Unfortunately the System Partition (C-Drive) will have been configured for the MSS, not your old PC. There will be many driver mis-matches that will prohibit proper operation.
You CAN, however, purchase an OEM copy of WHS and restore the PC using the old disks. Just configure the System Drive such that it will be the "first" drive, logically (Drive 0) and then install the other drives. Boot using the WHS DVD (in the server, not in a client as with the headless MSS) and choose the option to restore (repair? I forget the prompt) the server. You should be fine and all your data should be intact. (That said, I would recommend backing up anything you really want to keep before attempting this "just in case".)
Please post back here with your results -- I am sure others will be interested!
...JohnBick


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