I believe you can dual-boot WHS -- at least I was able to do so during the beta program. I have not tried it since.
Now, to clarify: You asked about WHS in an MSS forum and I gave you the WHS answer. If you really intended to ask it about the MSS the answer is different. It is probably "possible" but you would need to hook up video, keyboard, & mouse to use it and would need to add a CD/DVD to load the software and play some partitioning games on the system drive as well. I do not know of anyone who has tried this and don't know why anyone would want to with an MSS.
...JohnBick
EX475 + 3 1TB WD (2.5TB "pool", 1.5TB backup), 2 GB mmry, LE-1640, APC UPS
PC1: Vista/32 Ultimate SP1, 2x150 GB Raptor RAID-1 Sys (C) & 4x320GB RAID-5 Data (D)
PC2: Laptop, Win XP Home SP3
Linksys WRT54G v1.1, 2xNetGear GS105


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